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1,5-Asymmetric induction of chirality using π-allyltricarbonyliron lactone complexes: highly diastereoselective synthesis of α-functionalised carbonyl compounds
Christopher J. Hollowood, Steven V. Ley and Edward A. Wright Org. Biomol. Chem., 2003,1, 3208-3216
DOI:
10.1039/B306862E,
Paper
Silyl enol ethers derived from ketone functionalised π-allyltricarbonyliron lactone complexes undergo highly diastereoselective carbon–fluorine and carbon–oxygen bond formation reactions with excellent control at the α-stereogenic centre.