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Silyl enol ethers derived from ketone functionalised π-allyltricarbonyliron lactone complexes undergo highly diastereoselective carbon–fluorine and carbon–oxygen bond formation reactions with excellent control at the α-stereogenic centre.

Graphical abstract: 1,5-Asymmetric induction of chirality using π-allyltricarbonyliron lactone complexes: highly diastereoselective synthesis of α-functionalised carbonyl compounds

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