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Issue 7, 2003
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Halo-Derivatised Calix[4]tubes

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Abstract

Halo functionalisation of calix[4]tubes has been investigated through both derivatisation of individual calix[4]arenes and calix[4]tubes, using classical synthetic methods, to allow preparation of a series of novel derivatives. The solution and solid state properties are in accordance with the constituent calix[4]arenes adopting flattened cone arrangements which on complexation with potassium simplify to a regular cone. Electrospray and 1H NMR studies, combined with molecular modelling have been used to ascertain the metal binding of this new series of cryptand like ionophores, demonstrating their retained selectivity for binding potassium over other Group 1 metals and the dependence on counter anion in the weak binding of silver.

Graphical abstract: Halo-Derivatised Calix[4]tubes

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Publication details

The article was received on 18 Nov 2002, accepted on 17 Feb 2003 and first published on 12 Mar 2003


Article type: Paper
DOI: 10.1039/B211303A
Org. Biomol. Chem., 2003,1, 1232-1239

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    Halo-Derivatised Calix[4]tubes

    S. E. Matthews, V. Felix, M. G. B. Drew and P. D. Beer, Org. Biomol. Chem., 2003, 1, 1232
    DOI: 10.1039/B211303A

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