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Issue 3, 2003
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Enhanced π⋯π interactions in α,β-unsaturated carbonyls

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Abstract

High level ab initio calculations on complexes of benzene with acrolein and ethene reveal that π⋯π interactions to electron deficient acrolein are remarkably similar to those found in the benzene dimer.

Graphical abstract: Enhanced π⋯π interactions in α,β-unsaturated carbonyls

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Supplementary files

Article information


Submitted
24 Oct 2002
Accepted
12 Dec 2002
First published
10 Jan 2003

Org. Biomol. Chem., 2003,1, 457-459
Article type
Communication

Enhanced π⋯π interactions in α,β-unsaturated carbonyls

L. D. Harris, J. A. Platts and N. C. O. Tomkinson, Org. Biomol. Chem., 2003, 1, 457
DOI: 10.1039/B210497K

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