A novel organic-inorganic hybrid material with fluorescent emission: [Cd(PT)(H2O)]n(PT = phthalate)

Shutao Wang; Yu Hou; Enbo Wang; Yangguang Li; Lin Xu; Jun Peng; Shuxia Liu; Changwen Hu

doi:10.1039/B211358A

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A novel organic-inorganic hybrid material with fluorescent emission: [Cd(PT)(H₂O)]_n (PT = phthalate)†

Shutao Wang,^a Yu Hou,^a Enbo Wang,*^ab Yangguang Li,^a Lin Xu,^a Jun Peng,^a Shuxia Liu^a and Changwen Hu^a

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* Corresponding authors

^a Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, P. R. China
E-mail: wangenbo@public.cc.jl.cn
Fax: +86 431 568 4009

^b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China

Abstract

The novel organic-inorganic hybrid material [Cd(PT)(H₂O)]_n (1; PT = phthalate) has been hydrothermally synthesized. The X-ray diffraction study reveals that 1 exhibits an interesting two-dimensional (2D) honeycomb framework constructed from [CdO₇] single helical chains linked via oxygen atoms of the PT ligands, which adopt the μ₆-bridging coordination mode. A study of the physical properties of 1 demonstrates that it exhibits a strong fluorescent emission in the solid state at room temperature.

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Article information

DOI: https://doi.org/10.1039/B211358A
Article type: Paper
Submitted: 18 Nov 2002
Accepted: 18 Feb 2003
First published: 29 May 2003

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New J. Chem., 2003,27, 1144-1147

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A novel organic-inorganic hybrid material with fluorescent emission: [Cd(PT)(H₂O)]_n (PT = phthalate)

S. Wang, Y. Hou, E. Wang, Y. Li, L. Xu, J. Peng, S. Liu and C. Hu, New J. Chem., 2003, 27, 1144 DOI: 10.1039/B211358A

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