Issue 1, 2003
From the journal:

Mendeleev Communications

Adducts of ArSCl with vinyl ethers or esters as synthones in geminal alkylation

William A. Smit,*a   Alexei V. Gromovb  and  Elisey A. Yagodkina  

* Corresponding authors

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation, Leninsky prospekt, 47, Moscow, Russian Federation
E-mail: smt@ioc.ac.ru

b Higher Chemical College, Russian Academy of Sciences, Moscow, Russian Federation, Miusskaya ploshchad, 9, Moscow, Russian Federation

Abstract

The in situ-prepared adducts of arylsulfenyl chloride and vinyl ethers (esters) were employed as synthetic equivalents of 1,1-bis-electrophiles in the Lewis acid-promoted reaction sequence with two different carbon nucleophiles resulting in the formation of geminal bisalkylation products.

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Article information

DOI
https://doi.org/10.1070/MC2003v013n01ABEH001710
Article type
Paper
Submitted
08 Jan 2003

Mendeleev Commun., 2003,13, 21-23

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Adducts of ArSCl with vinyl ethers or esters as synthones in geminal alkylation

W. A. Smit, A. V. Gromov and E. A. Yagodkin, Mendeleev Commun., 2003, 13, 21 DOI: 10.1070/MC2003v013n01ABEH001710

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