Chloro(octaphenyltetraazaporphyrinato)indium(III) [(Cl)InOPTAP] dissociates easily in slightly acidified dichloromethane solutions (0.001–0.01 M CF3COOH) after addition of tetraethylammonium chloride; the observed catalytic effect of chloride anions is due to their additional cis-coordination to the In atom with formation of the dianionic complex [(Cl)3InOPTAP]2–.
Unusual catalytic effect of halide anions in the protolytic dissociation of indium(III) octaphenyltetraazaporphyrins
S. S. Ivanova and P. A. Stuzhin, Mendeleev Commun., 2003, 13, 17 DOI: 10.1070/MC2003v013n01ABEH001704
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