Cyclometallation on platinum(ii) complexes; the role of the solvent and added base donor capability on the reaction mechanisms†
Abstract
The reaction of PhCHNCH2CH2NMe2 with [PtCl2S2]
(S = SMe2 or
NCH2CH2NMe2)]
(1) in which the
NCH2CH2NMe2)]
(2) has been obtained by refluxing a