Issue 13, 2003
From the journal:

Dalton Transactions

Structural characterisation of a water intercalated bis-amide tecton and copper promoted monohydration of a dinitrile

Jens K. Bjernemose,a   Christine J. McKenzie,a   Paul R. Raithbyb  and  Simon J. Teatc  

a Department of Chemistry, University of Southern Denmark, Odense Campus, 5230 Odense M, Denmark
E-mail: chk@chem.sdu.dk
Fax: 45 6615 8780
Tel: 45 6550 2518

b Department of Chemistry, University of Bathy, Claverton Down, UK

c CLRC Daresbury Laboratory, Daresbury, Warrington, UK

Abstract

Chains of H-bonded water intercalated bis-amide pairs were found in the structure of {[Cu(cdc)2(OH2)]·H2O}∞ (1) (cdc− = carbamoyldicyanomethanide); specific hydration of one nitrile group of the cdc− ligands of 1 to give the previously unknown anion cyanomalonamidate (cyma−) as a ligand in [Cu(cyma)2]·H2O is possible.

Graphical abstract: Structural characterisation of a water intercalated bis-amide tecton and copper promoted monohydration of a dinitrile

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Article information

DOI
https://doi.org/10.1039/B306169H
Article type
Communication
Submitted
02 Jun 2003
Accepted
04 Jun 2003
First published
11 Jun 2003

Dalton Trans., 2003, 2639-2640

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Structural characterisation of a water intercalated bis-amide tecton and copper promoted monohydration of a dinitrile

J. K. Bjernemose, C. J. McKenzie, P. R. Raithby and S. J. Teat, Dalton Trans., 2003, 2639 DOI: 10.1039/B306169H

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