Issue 11, 2003
From the journal:

Dalton Transactions

A bis(imido)organoarsenate dianion incorporating n-butyllithium

May C. Copsey,a   John C. Jeffery,a   Angela P. Leedham,a   Christopher A. Russell*a  and  John M. Slatterya  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK
E-mail: Chris.Russell@bristol.ac.uk

Abstract

Reaction of AsCl3 with 3 equivalents of (2-OPh)C6H4NH2 in toluene/NEt3, followed by metallation with 3 equivalents of BunLi produces a bis(imido)organoarsenate dianion as a lithium salt which co-complexes BunLi to form a dimeric cage with a 14 membered core.

Graphical abstract: A bis(imido)organoarsenate dianion incorporating n-butyllithium

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Article information

DOI
https://doi.org/10.1039/B304307J
Article type
Communication
Submitted
22 Apr 2003
Accepted
07 May 2003
First published
13 May 2003

Dalton Trans., 2003, 2103-2104

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A bis(imido)organoarsenate dianion incorporating n-butyllithium

M. C. Copsey, J. C. Jeffery, A. P. Leedham, C. A. Russell and J. M. Slattery, Dalton Trans., 2003, 2103 DOI: 10.1039/B304307J

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