Issue 11, 2003
From the journal:

Dalton Transactions

Synthesis and characterization of a decacobalt carbonyl cluster with two semi-interstitial phosphorus atoms

Chang Seop Hong,a   Louise A. Berbena  and  Jeffrey R. Long*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, California 94720-1460, USA
E-mail: jlong@cchem.berkeley.edu

Abstract

A paramagnetic cobalt carbonyl cluster, [Co10P2(CO)23H]2−, containing two partially-encapsulated phosphorus atoms is synthesized through the reaction of [Co6(CO)15]2− and [Co(CO)4]− with PBr3 in THF.

Graphical abstract: Synthesis and characterization of a decacobalt carbonyl cluster with two semi-interstitial phosphorus atoms

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Article information

DOI
https://doi.org/10.1039/B302383D
Article type
Communication
Submitted
03 Mar 2003
Accepted
07 Apr 2003
First published
16 Apr 2003

Dalton Trans., 2003, 2119-2120

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Synthesis and characterization of a decacobalt carbonyl cluster with two semi-interstitial phosphorus atoms

C. S. Hong, L. A. Berben and J. R. Long, Dalton Trans., 2003, 2119 DOI: 10.1039/B302383D

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