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Issue 5, 2003
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Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions

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Abstract

The increase of the curvature of the interface between the rigid mesogenic core and the aliphatic chains in the hexacatenar tridentate ligand L3 overcomes the considerable expansion brought by the complexation of bulky metallic cores, thus leading to organized cubic mesophases for monometallic zincII and lanthanideIII complexes.

Graphical abstract: Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions

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The article was received on 04 Dec 2002, accepted on 24 Jan 2003 and first published on 03 Feb 2003


Article type: Communication
DOI: 10.1039/B211902A
Dalton Trans., 2003, 769-772

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    Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions

    E. Terazzi, J. Bénech, J. Rivera, G. Bernardinelli, B. Donnio, D. Guillon and C. Piguet, Dalton Trans., 2003, 769
    DOI: 10.1039/B211902A

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