Aminoallenylidene complexes of ruthenium(ii) from the regioselective addition of secondary amines to butatrienylidene intermediates: a combined experimental and theoretical study of the hindered rotation around the CN-bond†
Abstract
Aminoallenylidene complexes trans-[Cl(dppm)2RuC3(NRR′)(CH3)]+ are obtained from the regioselective addition of