Issue 3, 2003
From the journal:

Dalton Transactions

Diphenylvinylphosphine (DPVP) complexes containing the (η5-MeC5H4)Ru(ii) moiety: synthesis, characterization and reactions†

Dorota Duraczyńskaa  and  John H. Nelson*a  

* Corresponding authors

a Department of Chemistry/216, University of Nevada – Reno, Reno, Nevada 89557-0020, USA

Abstract

The complex [(η5-MeC5H4)Ru(DPVP)2(CH3CN)]PF6 (4) (DPVP = Ph2PCH[double bond, length as m-dash]CH2) loses CH3CN under vacuum to produce the phosphaallyl complex [(η5-MeC5H4)Ru(η1-DPVP)(η3-DPVP)]PF6 (6) and reacts with Me3SiC[triple bond, length as m-dash]CH and PhC[triple bond, length as m-dash]CH in CH2Cl2–CH3OH solutions to form the methoxymethylcarbene [(η5-MeC5H4)(DPVP)2Ru[double bond, length as m-dash]C(OCH3)(CH3)]PF6 (7) and the carbonyl complex [(η5-MeC5H4)Ru(DPVP)2(CO)]PF6 (8), respectively. In contrast [(η5-MeC5H4)Ru(DPVP)(CO)(CH3CN)]PF6 (15) does not lose CH3CN to form a phosphaallyl complex. The structures of the complexes described herein have been deduced from elemental analyses, infrared spectroscopy, 1H, 13C{1H}, 1H NOE, where appropriate by 31P{1H} NMR spectroscopy and in eight cases by X-ray crystallography.

Graphical abstract: Diphenylvinylphosphine (DPVP) complexes containing the (η5-MeC5H4)Ru(ii) moiety: synthesis, characterization and reactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B210492J
Article type
Paper
Submitted
24 Oct 2002
Accepted
27 Nov 2002
First published
13 Jan 2003

Dalton Trans., 2003, 449-457

Permissions

Request permissions

Diphenylvinylphosphine (DPVP) complexes containing the (η5-MeC5H4)Ru(II) moiety: synthesis, characterization and reactions

D. Duraczyńska and J. H. Nelson, Dalton Trans., 2003, 449 DOI: 10.1039/B210492J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements