Issue 90, 2003
From the journal:

CrystEngComm

Lithium salicylate monohydrate: A layer structure with carboxylate-bridged Δ- and Λ-[(H2O)Li+]∞ helices

Frank Wiesbrocka  and  Hubert Schmidbaur*a  

* Corresponding authors

a Anorganisch-chemisches Institut, Technische Universität München, Lichtenbergstrasse 4, Garching, Germany
E-mail: H.Schmidbaur@lrz.tum.de
Fax: +49 89 289 13125
Tel: +49 89 289 13130

Abstract

Lithium salicylate crystallizes from aqueous solutions as the monohydrate (space group P21/c). In its layer structure, alternating Δ- and Λ-[(H2O)Li+]∞ helices run parallel along the b-axis. These helices are double-bridged at the tetracoordinate lithium cations by the carboxylate groups of the salicylate anions.

Graphical abstract: Lithium salicylate monohydrate: A layer structure with carboxylate-bridged Δ- and Λ-[(H2O)Li+]∞ helices

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Article information

DOI
https://doi.org/10.1039/B312892J
Article type
Paper
Submitted
15 Oct 2003
Accepted
21 Nov 2003
First published
05 Dec 2003

CrystEngComm, 2003,5, 503-505

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Lithium salicylate monohydrate: A layer structure with carboxylate-bridged Δ- and Λ-[(H2O)Li+]∞ helices

F. Wiesbrock and H. Schmidbaur, CrystEngComm, 2003, 5, 503 DOI: 10.1039/B312892J

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