Issue 45, 2003
From the journal:

CrystEngComm

Lithium l-hydrogen-α-glutamate: A layer structure with asymmetrical tunnels formed by nets with two different macrocycles

Frank Wiesbrocka  and  Hubert Schmidbaur*a  

* Corresponding authors

a Anorganisch-chemisches Institut, Technische Universität München, Lichtenbergstrasse 4, Garching, Germany
E-mail: H.Schmidbaur@lrz.tum.de
Fax: +49 89 289 13125
Tel: +49 89 289 13131

Abstract

Anhydrous lithium L-hydrogen-α-glutamate Li[L-α-GluH] crystallizes from water with a layer structure (non-centrosymmetric space group P1) in which the tetracoordinate lithium cations are bridged by the glutamate anions in their ammonium form (–NH3+). The resulting 12- and 16-membered rings allow for tunnels running perpendicular to each other in the layers.

Graphical abstract: Lithium l-hydrogen-α-glutamate: A layer structure with asymmetrical tunnels formed by nets with two different macrocycles

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Article information

DOI
https://doi.org/10.1039/B304689C
Article type
Paper
Submitted
29 Apr 2003
Accepted
20 Jun 2003
First published
30 Jun 2003

CrystEngComm, 2003,5, 262-264

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Lithium L-hydrogen-α-glutamate: A layer structure with asymmetrical tunnels formed by nets with two different macrocycles

F. Wiesbrock and H. Schmidbaur, CrystEngComm, 2003, 5, 262 DOI: 10.1039/B304689C

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