Issue 28, 2003
From the journal:

CrystEngComm

Inclusion compounds of 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol with DMF and DMSO: structures, selectivity and kinetics of desolvation†

Mino R. Caira,a   Ayesha Jacobs,*b   Luigi R. Nassimbenia  and  Fumio Todac  

* Corresponding authors

a Department of Chemistry, University of Cape Town, Rondebosch, South Africa

b Department of Chemistry, University of Port Elizabeth, Port Elizabeth, South Africa
E-mail: chaaaj@upe.ac.za

c Department of Chemistry, Okayama University of Science, Okayama, Japan

Abstract

The host (H) 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol includes N,N-dimethylformamide (DMF) and dimethyl sulfoxide (DMSO). The structures of the isostructural inclusion compounds H·2DMF and H·2DMSO have been determined. Competition experiments, kinetics of desolvation and guest exchange reactions were performed and the results rationalised in terms of the structural features of the host–guest compounds.

Graphical abstract: Inclusion compounds of 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol with DMF and DMSO: structures, selectivity and kinetics of desolvation

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Article information

DOI
https://doi.org/10.1039/B302548A
Article type
Paper
Submitted
05 Mar 2003
Accepted
01 May 2003
First published
15 May 2003

CrystEngComm, 2003,5, 150-153

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Inclusion compounds of 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol with DMF and DMSO: structures, selectivity and kinetics of desolvation

M. R. Caira, A. Jacobs, L. R. Nassimbeni and F. Toda, CrystEngComm, 2003, 5, 150 DOI: 10.1039/B302548A

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