Issue 19, 2003
From the journal:

CrystEngComm

The ‘globule–globule’ hybrid dicarbaborane–polyoxometallate salt, [C2B10H11CH2NHCH(CH3)2]4[W10O32][H2O]2[(CH3)2CO]4

Ramón Macías,†*ab   John D. Kennedy,a   Mark Thornton-Petta  and  Pascual Románb  

* Corresponding authors

a Department of Chemistry, University of Leeds, Leeds, UK

b Departamento de Química Inorgánica, Universidad del País Vasco, Apartado 644, Bilbao, Spain

Abstract

The ‘globule–globule’ salt, [C2B10H11CH2NHCH(CH3)2]4[W10O32][H2O]2[(CH3)2CO]4, contains new iminium dicarbaborane cluster cations, [C2B10H11CH2NH[double bond, length as m-dash]CH(CH3)2]+, and decatungstate cluster anions, [W10O32]4−, linked by hydrogen bonded H2O and (CH3)2CO solvent molecules to form a hydrophilic/hydrophobic lamellar structure.

Graphical abstract: The ‘globule–globule’ hybrid dicarbaborane–polyoxometallate salt, [C2B10H11CH2NHCH(CH3)2]4[W10O32][H2O]2[(CH3)2CO]4

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Article information

DOI
https://doi.org/10.1039/B302341A
Article type
Paper
Submitted
28 Feb 2003
Accepted
26 Mar 2003
First published
09 Apr 2003

CrystEngComm, 2003,5, 93-95

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The ‘globule–globule’ hybrid dicarbaborane–polyoxometallate salt, [C2B10H11CH2NHCH(CH3)2]4[W10O32][H2O]2[(CH3)2CO]4

R. Macías, J. D. Kennedy, M. Thornton-Pett and P. Román, CrystEngComm, 2003, 5, 93 DOI: 10.1039/B302341A

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