Issue 7, 2003
From the journal:

CrystEngComm

Extremely short intermolecular N(sp2)⋯Cl contact in the bis-2,4-(biphenyl-4-yloxy)-6-chloro-[1,3,5]triazine crystal

Nikoletta Báthori,ab   László Bihátsi,b   Petra Bombicza  and  Mátyás Czugler*a  

* Corresponding authors

a Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, H-1525 Budapest, Hungary
E-mail: czugler@chemres.hu

b Department of Inorganic Chemistry, Budapest University of Technology and Economics, H-1521 Budapest, Hungary
E-mail: bihatsi@mail.bme.hu

Abstract

The crystal structure of bis-2,4-(biphenyl-4-yloxy)-6-chloro-[1,3,5]triazine (1) reveals an extremely short 3.05 Å N⋯Cl interaction. The butterfly-shaped molecule 1 lies on a mirror plane thus forming an infinite polymeric chain along the c crystallographic axis via N⋯Cl interactions. Structural databank (CSD) analysis shows that this kind of short contact exists primarily in mirror-symmetric molecules.

Graphical abstract: Extremely short intermolecular N(sp2)⋯Cl contact in the bis-2,4-(biphenyl-4-yloxy)-6-chloro-[1,3,5]triazine crystal

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Article information

DOI
https://doi.org/10.1039/B211206J
Article type
Paper
Submitted
14 Nov 2002
Accepted
09 Jan 2003
First published
17 Jan 2003

CrystEngComm, 2003,5, 42-44

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Extremely short intermolecular N(sp2)⋯Cl contact in the bis-2,4-(biphenyl-4-yloxy)-6-chloro-[1,3,5]triazine crystal

N. Báthori, L. Bihátsi, P. Bombicz and M. Czugler, CrystEngComm, 2003, 5, 42 DOI: 10.1039/B211206J

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