Issue 24, 2003

A ferrocene based palladacyclic precatalyst for the Suzuki cross-coupling of aryl chlorides

Abstract

Addition of palladium acetate to 2-(dicyclohexylphosphino)phenylferrocene gave palladacycle 16 that is a very effective precatalyst for the Suzuki cross-coupling of aryl chlorides at room temperature (1 mol% 16) or 60 °C (≥ 0.01 mol% 16).

Graphical abstract: A ferrocene based palladacyclic precatalyst for the Suzuki cross-coupling of aryl chlorides

Article information

Article type
Communication
Submitted
29 Aug 2003
Accepted
16 Oct 2003
First published
07 Nov 2003

Chem. Commun., 2003, 3002-3003

A ferrocene based palladacyclic precatalyst for the Suzuki cross-coupling of aryl chlorides

F. X. Roca and C. J. Richards, Chem. Commun., 2003, 3002 DOI: 10.1039/B310526A

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