Issue 22, 2003

Two-dimensional metamagnet composed of cyano-bridged CuII–WV bimetallic assembly

Abstract

Two-dimensional cyanide-bridged copper(II) octacyanotungstates(V), [{Cu(3-CNpy)2(H2O)}2{Cu(3-CNpy)2(H2O)2}{W(CN)8}2] (3-CNpy = 3-cyanopyridine) (1) and [{Cu(4-CNpy)2}2{Cu(4-CNpy)2(H2O)2}{W(CN)8}2]·6H2O (4-CNpy = 4-cyanopyridine) (2), were prepared and these compounds exhibited metamagnetic behavior with Néel temperatures of 8.0 K (1) and 4.4 K (2).

Graphical abstract: Two-dimensional metamagnet composed of cyano-bridged CuII–WV bimetallic assembly

Supplementary files

Article information

Article type
Communication
Submitted
01 Sep 2003
Accepted
29 Sep 2003
First published
20 Oct 2003

Chem. Commun., 2003, 2772-2773

Two-dimensional metamagnet composed of cyano-bridged CuII–WV bimetallic assembly

S. Ohkoshi, Y. Arimoto, T. Hozumi, H. Seino, Y. Mizobe and K. Hashimoto, Chem. Commun., 2003, 2772 DOI: 10.1039/B310456G

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