Issue 24, 2003
From the journal:

Chemical Communications

Structure and electronic properties of an asymmetric thiolate-bridged binuclear complex: a model for the active site of acetyl CoA synthase†

Qiang Wang,a   Alexander J. Blake,a   E. Stephen Davies,a   Eric J. L. McInnes,b   Claire Wilsona  and  Martin Schröder*a  

* Corresponding authors

a School of Chemistry, The University of Nottingham, Nottingham, UK
E-mail: M.Schroder@nottingham.ac.uk
Fax: + 44(0)115 9513563
Tel: + 44(0)115 9513490

b EPSRC EPR Service Centre, Department of Chemistry, The University of Manchester, Oxford Road, Manchester, UK

Abstract

The asymmetric binuclear complex [(dppe)Ni(μ-‘S, S’)Ni(L)](PF6)2 [L = (N, N′-diethyl-3,7-diazanonane-1,9-dithiolato)2−] shows a reversible one-electron reduction to afford a mixed-valent Ni(II)·Ni(I) species; the reduced complex has been characterised by EPR spectroscopy and mimics the redox active Nip site in the active A-cluster of acetyl coenzyme A synthase.

Graphical abstract: Structure and electronic properties of an asymmetric thiolate-bridged binuclear complex: a model for the active site of acetyl CoA synthase

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Article information

DOI
https://doi.org/10.1039/B310183E
Article type
Communication
Submitted
27 Aug 2003
Accepted
14 Oct 2003
First published
03 Nov 2003

Chem. Commun., 2003, 3012-3013

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Structure and electronic properties of an asymmetric thiolate-bridged binuclear complex: a model for the active site of acetyl CoA synthase

Q. Wang, A. J. Blake, E. S. Davies, E. J. L. McInnes, C. Wilson and M. Schröder, Chem. Commun., 2003, 3012 DOI: 10.1039/B310183E

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