Issue 20, 2003
From the journal:

Chemical Communications

Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand

Markus Albrecht,*a   Sören Schmid,a   Marita deGroot,a   Patrick Weisb  and  Roland Fröhlichc  

* Corresponding authors

a Institut für Organische Chemie der RWTH-Aachen, Professor-Pirlet-Straße 1, D-52074 Aachen, Germany
E-mail: markus.albrecht@oc.rwth-aachen.de
Fax: +49 241 80 92385
Tel: +49 241 80 94678

b Institut für Physikalische Chemie der Universität Karlsruhe, Fritz-Haber-Weg, D-76128 Karlsruhe, Germany

c Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, D-48149 Münster, Germany

Abstract

Chiral tetraketone ligands are obtained by Claisen-type condensation of 4-bromoacetophenone with the acetone ketal of L-tartraic acid diethylester and lead with gallium(III) or iron(III) ions in self-assembly processes to dinuclear helicate-type cryptands which are able to bind lithium cations.

Graphical abstract: Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B309026D
Article type
Communication
Submitted
31 Jul 2003
Accepted
05 Sep 2003
First published
19 Sep 2003

Chem. Commun., 2003, 2526-2527

Permissions

Request permissions

Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand

M. Albrecht, S. Schmid, M. deGroot, P. Weis and R. Fröhlich, Chem. Commun., 2003, 2526 DOI: 10.1039/B309026D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements