Issue 20, 2003
From the journal:

Chemical Communications

Catalytic C[double bond, length as m-dash]N bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands

Tiow-Gan Ong,a   Glenn P. A. Yapb  and  Darrin S. Richeson*a  

* Corresponding authors

a Department of Chemistry and the Center for Catalysis Research and Innovation, University of Ottawa, Ottawa, Ontario
E-mail: darrin@science.uottawa.ca.

b Department of Chemistry and Biochemistry, University of Delaware, Newark, DE, 19716

Abstract

A family of guanidinate-supported imido metal complexes are novel, effective catalysts for C[double bond, length as m-dash]N metathesis of alkyl and aryl carbodiimides and evidence suggests that this reaction proceeds via a sequential addition/elimination pathway.

Graphical abstract: Catalytic C [[double bond, length as m-dash]] N bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands

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Article information

DOI
https://doi.org/10.1039/B308710G
Article type
Communication
Submitted
24 Jul 2003
Accepted
02 Sep 2003
First published
19 Sep 2003

Chem. Commun., 2003, 2612-2613

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Catalytic C[double bond, length as m-dash]N bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands

T. Ong, G. P. A. Yap and D. S. Richeson, Chem. Commun., 2003, 2612 DOI: 10.1039/B308710G

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