Issue 20, 2003
From the journal:

Chemical Communications

An EPR study of the intramolecular dynamics in o-semiquinonic nickel complexes with a diphosphorous pincer ligand†

Konstantin A. Kozhanov,a   Michael P. Bubnov,*a   Vladimir K. Cherkasov,a   Georgy K. Fukina  and  Gleb A. Abakumova  

* Corresponding authors

a G. A. Razuvaev Institute of organometallic chemistry of Russian Academy of Sciences, 49, Tropinina str. 603950 Nizhny Novgorod, Russian Federation
E-mail: bmp@imoc.sinn.ru
Fax: +7 8312 127497
Tel: +7 8312 127682

Abstract

Square pyramidal o-semiquinonic nickel complexes with 2,6-bis(diphenylphosphinomethyl)phenyl have a flexible coordination sphere and exist in solution as the mixture of tautomers rapidly, according to EPR time scale, interconverting at room temperature.

Graphical abstract: An EPR study of the intramolecular dynamics in o-semiquinonic nickel complexes with a diphosphorous pincer ligand

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Article information

DOI
https://doi.org/10.1039/B308701H
Article type
Communication
Submitted
24 Jul 2003
Accepted
04 Sep 2003
First published
22 Sep 2003

Chem. Commun., 2003, 2610-2611

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An EPR study of the intramolecular dynamics in o-semiquinonic nickel complexes with a diphosphorous pincer ligand

K. A. Kozhanov, M. P. Bubnov, V. K. Cherkasov, G. K. Fukin and G. A. Abakumov, Chem. Commun., 2003, 2610 DOI: 10.1039/B308701H

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