Dipyridylketone binding and subsequent C–C bond insertion reactions at cyclopentadienylrhodium
Abstract
UV irradiation of a solution of (η5-C5H5)bis(ethene)rhodium in the presence of 2,2′-dipyridylketone yields (η5-C5H5)Rh(κ2-N, O-2,2′-dipyridylketone) which inserts