Issue 18, 2003
From the journal:

Chemical Communications

Monomeric (dialkylamino)boranes: a new and efficient boron source in palladium catalyzed C–B bond formation with aryl halides

Lisenn Euzenat,a   David Horhant,a   Yann Ribourdouille,a   Christophe Duriez,a   Gilles Alcaraz*a  and  Michel Vaultiera  

* Corresponding authors

a S. E. S. O. UMR-CNRS 6510, Université de Rennes1-Beaulieu, F-35042, Rennes, France
E-mail: gilles.alcaraz@univ-rennes1.fr
Fax: 33 22323 6955
Tel: 33 22323 5672

Abstract

Thermal decomposition of hindered amine-borane adducts leads in high yields to monomeric (dialkylamino)boranes R1R2N–BH2 (R1 and R2 = alkyl) that are new and efficient boron-sources in the Pd0 catalyzed borylation reaction affording monomeric aryl(dialkylamino)boranes R1R2N–BHR3 (R3 = aryl).

Graphical abstract: Monomeric (dialkylamino)boranes: a new and efficient boron source in palladium catalyzed C–B bond formation with aryl halides

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Article information

DOI
https://doi.org/10.1039/B306874A
Article type
Communication
Submitted
17 Jun 2003
Accepted
17 Jul 2003
First published
31 Jul 2003

Chem. Commun., 2003, 2280-2281

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Monomeric (dialkylamino)boranes: a new and efficient boron source in palladium catalyzed C–B bond formation with aryl halides

L. Euzenat, D. Horhant, Y. Ribourdouille, C. Duriez, G. Alcaraz and M. Vaultier, Chem. Commun., 2003, 2280 DOI: 10.1039/B306874A

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