Issue 18, 2003
From the journal:

Chemical Communications

Poly(ruthenium carbonyl spirobifluorenylporphyrin): a new polymer used as a catalytic device for carbene transfer†

Cyril Poriel,a   Yann Ferrand,a   Paul le Maux,a   Christine Paul,a   Joëlle Rault-Berthelot*b  and  Gerard Simonneaux*a  

* Corresponding authors

a Laboratoire de Chimie Organométallique et Biologique, UMR CNRS 6509, Université de Rennes I, 35042 Rennes cedex, France
E-mail: gerard.simonneaux@univ-rennes1.fr
Fax: 02 23 23 56 37
Tel: 02 23 23 62 85:

b Laboratoire d'Electrochimie Moléculaire et Macromoléculaire, UMR CNRS 6510, Université de Rennes I, 35042 Rennes cedex, France
E-mail: joelle.rault@univ-rennes1.fr
Fax: 02 23 23 67 32
Tel: 02 23 23 59 40

Abstract

Oxidative electropolymerization of tetraspirobifluorenyl porphyrin ruthenium(II) carbonyl complexes can be used to coat Pt electrodes with polymeric films; after being removed from the electrode, these polymeric materials are able to catalyze the heterogeneous cyclopropanations and 2,3 sigmatropic rearrangements with ethyl diazoacetate.

Graphical abstract: Poly(ruthenium carbonyl spirobifluorenylporphyrin): a new polymer used as a catalytic device for carbene transfer

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Article information

DOI
https://doi.org/10.1039/B306021G
Article type
Communication
Submitted
30 May 2003
Accepted
01 Aug 2003
First published
19 Aug 2003

Chem. Commun., 2003, 2308-2309

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Poly(ruthenium carbonyl spirobifluorenylporphyrin): a new polymer used as a catalytic device for carbene transfer

C. Poriel, Y. Ferrand, P. le Maux, C. Paul, J. Rault-Berthelot and G. Simonneaux, Chem. Commun., 2003, 2308 DOI: 10.1039/B306021G

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