Issue 15, 2003
From the journal:

Chemical Communications

Side chain-directed assembly of triangular molecular panels into a tetrahedron vs. open cone†

Michito Yoshizawa,a   Muneki Nagao,a   Kazuhiko Umemoto,a   Kumar Biradha,a   Makoto Fujita,*a   Shigeru Sakamotob  and  Kentaro Yamaguchib  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Corporation (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: mfujita@appchem.t.u-tokyo.ac.jp

b Chemical Analysis Center, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

Abstract

Despite their structural similarity, triangular tetradentate ligands 2b and 2c experience different assembly pathways on complexation with (en)Pd(NO3)2 to give M8L4 tetrahedral (3) and open cone (4) structures, respectively, due to steric restriction by side chains at the corner or on the edge of the ligands.

Graphical abstract: Side chain-directed assembly of triangular molecular panels into a tetrahedron vs. open cone

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B305129C
Article type
Communication
Submitted
08 May 2003
Accepted
19 Jun 2003
First published
01 Jul 2003

Chem. Commun., 2003, 1808-1809

Permissions

Request permissions

Side chain-directed assembly of triangular molecular panels into a tetrahedron vs. open cone

M. Yoshizawa, M. Nagao, K. Umemoto, K. Biradha, M. Fujita, S. Sakamoto and K. Yamaguchi, Chem. Commun., 2003, 1808 DOI: 10.1039/B305129C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements