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Issue 14, 2003
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[{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence

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Abstract

The complex [{AuTl(C6Cl5)2(toluene)}2(dioxane)] displays a structure with the thallium(I) center in an unprecedented trigonal planar environment, showing the shortest Au–Tl interaction ever found, a toluene molecule in a η6-mode and the “disappearance” of the Tl(I) inert pair, usually stereochemically active. These characteristics are responsible for its unusual luminescent behaviour.

Graphical abstract: [{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence

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Publication details

The article was received on 30 Apr 2003, accepted on 30 May 2003 and first published on 16 Jun 2003


Article type: Communication
DOI: 10.1039/B304835G
Chem. Commun., 2003, 1760-1761

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    [{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence

    E. J. Fernández, A. Laguna, J. M. López-de-Luzuriaga, M. Elena Olmos and J. Pérez, Chem. Commun., 2003, 1760
    DOI: 10.1039/B304835G

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