Issue 15, 2003
From the journal:

Chemical Communications

The seventeen- and eighteen-electron metallacarbaboranes [1,1,1-(CO)3-2-Ph-closo-1,2-MnCB9H9]n− (n = 1, 2): a structurally characterized, redox-related pair

Shaowu Du,a   Robert D. Farley,b   Jeremy N. Harvey,c   John C. Jeffery,c   Jason A. Kautz,a   John P. Maher,c   Thomas D. McGrath,a   Damien M. Murphy,b   T. Riis-Johannessenc  and  F. Gordon A. Stone*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Baylor University, Waco, Texas 76798-7348, USA
E-mail: gordon_stone@baylor.edu

b EPSRC National ENDOR Service, Cardiff University, Cardiff, UK

c School of Chemistry, University of Bristol, Bristol, UK

Abstract

An eleven-vertex manganese-monocarbaborane dianion, upon one-electron oxidation, gives a stable radical monoanion in which the unpaired electron is delocalized over the cluster.

Graphical abstract: The seventeen- and eighteen-electron metallacarbaboranes [1,1,1-(CO)3-2-Ph-closo-1,2-MnCB9H9]n− (n = 1, 2): a structurally characterized, redox-related pair

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Article information

DOI
https://doi.org/10.1039/B304101H
Article type
Communication
Submitted
11 Apr 2003
Accepted
10 Jun 2003
First published
26 Jun 2003

Chem. Commun., 2003, 1846-1847

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The seventeen- and eighteen-electron metallacarbaboranes [1,1,1-(CO)3-2-Ph-closo-1,2-MnCB9H9]n− (n = 1, 2): a structurally characterized, redox-related pair

S. Du, R. D. Farley, J. N. Harvey, J. C. Jeffery, J. A. Kautz, J. P. Maher, T. D. McGrath, D. M. Murphy, T. Riis-Johannessen and F. G. A. Stone, Chem. Commun., 2003, 1846 DOI: 10.1039/B304101H

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