Issue 15, 2003

Isolation and characterisation of transition and main group metal complexes supported by hydrogen-bonded zwitterionic polyphenolic ligands

Abstract

Reaction of Zr(OiPr)4 or Sn[N(SiMe3)2]2 with the tris-phenol amine ligand H3L(Me/Me) results in the formation of zirconium or tin complexes containing the new C3-symmetric zwitterionic ammonium-trisphenolate ligand HL2−, while increasing the steric bulk of the ligand results in the isolation of a zirconium complex containing the known trianionic ligand L3−.

Graphical abstract: Isolation and characterisation of transition and main group metal complexes supported by hydrogen-bonded zwitterionic polyphenolic ligands

Supplementary files

Article information

Article type
Communication
Submitted
02 Apr 2003
Accepted
23 May 2003
First published
19 Jun 2003

Chem. Commun., 2003, 1832-1833

Isolation and characterisation of transition and main group metal complexes supported by hydrogen-bonded zwitterionic polyphenolic ligands

M. G. Davidson, C. L. Doherty, A. L. Johnson and M. F. Mahon, Chem. Commun., 2003, 1832 DOI: 10.1039/B303618A

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