Issue 15, 2003
From the journal:

Chemical Communications

Preparation and structures of homoleptic Pu(iii) and U(iii) acetonitrile salts

Alejandro E. Enriquez,a   John H. Matonic,a   Brian L. Scotta  and  Mary P. Neu*a  

* Corresponding authors

a Actinide, Catalysis, and Separations Chemistry (C-SIC), Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico, 87545, USA
E-mail: mneu@lanl.gov
Fax: (505) 667-9905
Tel: (505) 667-7717

Abstract

Nine-coordinate homoleptic acetonitrile solvate complexes of Pu(III) and U(III) ions have been prepared through oxidation of Pu metal suspended in acetonitrile with metal-hexafluorophosphate salts and dissolution of UI3(THF)4 in acetonitrile, respectively.

Graphical abstract: Preparation and structures of homoleptic Pu(iii) and U(iii) acetonitrile salts

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Article information

DOI
https://doi.org/10.1039/B303558A
Article type
Communication
Submitted
01 Apr 2003
Accepted
27 May 2003
First published
23 Jun 2003

Chem. Commun., 2003, 1892-1893

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Preparation and structures of homoleptic Pu(III) and U(III) acetonitrile salts

A. E. Enriquez, J. H. Matonic, B. L. Scott and M. P. Neu, Chem. Commun., 2003, 1892 DOI: 10.1039/B303558A

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