Issue 12, 2003
From the journal:

Chemical Communications

The nature of the counter-anion can determine the rate of water exchange in a metal aqua complex†

Alessandro Barge,a   Mauro Botta,*a   David Parker*b  and  Horst Puschmannb  

* Corresponding authors

a Dipartimento di Scienze e Tecnologie Avanzate, Universita degli Studi del Piemonte Orientale, Corso Borsalino 54, I-10131 Alessandria, Italy

b Department of Chemistry, University of Durham, South Road, Durham, UK
E-mail: david.parker@dur.ac.uk, mauro.botta@unito.it

Abstract

The nature of the counter-anion determines the water exchange rate for a series of cationic gadolinium complexes in aqueous solution, as a consequence of the ordering effect that the anion imposes on the structure of the second hydration sphere.

Graphical abstract: The nature of the counter-anion can determine the rate of water exchange in a metal aqua complex

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Article information

DOI
https://doi.org/10.1039/B302211K
Article type
Communication
Submitted
25 Feb 2003
Accepted
23 Apr 2003
First published
16 May 2003

Chem. Commun., 2003, 1386-1387

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The nature of the counter-anion can determine the rate of water exchange in a metal aqua complex

A. Barge, M. Botta, D. Parker and H. Puschmann, Chem. Commun., 2003, 1386 DOI: 10.1039/B302211K

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