Issue 10, 2003
From the journal:

Chemical Communications

Reductive cleavage of the C–O bond of acetals and orthoesters: reduction by silane in the presence of a Rh–PPh3 complex

Tetsuo Ohta,*a   Tsugumi Michibata,a   Kazuyuki Yamada,a   Ryohei Omoria  and  Isao Furukawaa  

* Corresponding authors

a Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0394, Japan
E-mail: tota@mail.doshisha.ac.jp

Abstract

Reductions of acetals to ethers and of orthoester to acetal by hydrosilane using rhodium catalyst are described.

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Article information

DOI
https://doi.org/10.1039/B302124F
Article type
Communication
Submitted
24 Feb 2003
Accepted
01 Apr 2003
First published
17 Apr 2003

Chem. Commun., 2003, 1192-1193

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Reductive cleavage of the C–O bond of acetals and orthoesters: reduction by silane in the presence of a Rh–PPh3 complex

T. Ohta, T. Michibata, K. Yamada, R. Omori and I. Furukawa, Chem. Commun., 2003, 1192 DOI: 10.1039/B302124F

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