A novel migrative addition reaction of hydrazines to the diketone derivative of C60

Sho-ichi Iwamatsu; Fumiaki Ono; Shizuaki Murata

doi:10.1039/B302080K

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A novel migrative addition reaction of hydrazines to the diketone derivative of C₆₀†

Sho-ichi Iwamatsu,*^a Fumiaki Ono^a and Shizuaki Murata^ab

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* Corresponding authors

^a Graduate School of Environmental Studies, Nagoya University, Nagoya 464-8601, Japan
E-mail: iwmt@urban.env.nagoya-u.ac.jp
Fax: +81-52-789-5641
Tel: +81-52-789-4849

^b CREST, Japan Science and Technology Corporation (JST), Kawaguchi, Japan

Abstract

A novel addition reaction of an aromatic hydrazine to the diketone derivative of C₆₀ occurs highly regioselectively with an unusual migration of two hydrogen atoms from the hydrazine to the fullerene and affords a fluorescent product having a methylene carbon along the orifice.

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Article information

DOI: https://doi.org/10.1039/B302080K
Article type: Communication
Submitted: 21 Feb 2003
Accepted: 04 Apr 2003
First published: 02 May 2003

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Chem. Commun., 2003, 1268-1269

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A novel migrative addition reaction of hydrazines to the diketone derivative of C₆₀

S. Iwamatsu, F. Ono and S. Murata, Chem. Commun., 2003, 1268 DOI: 10.1039/B302080K

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