Issue 10, 2003
From the journal:

Chemical Communications

A stable alkyl hydride of a first row transition metal

Leonard A. MacAdams,a   Gerald P. Buffone,a   Christopher D. Incarvito,a   James A. Golen,a   Arnold L. Rheingolda  and  Klaus H. Theopold*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Center for Catalytic Science and Technology, University of Delaware, Newark, DE 19716, USA
E-mail: theopold@udel.edu
Fax: (302)831-6335
Tel: (302)831-1546

Abstract

Hydrogenolysis of a Cr(III) dialkyl precursor produced a binuclear chromium complex with a bridging hydride and a bridging alkyl; this structurally characterized organometallic compound is thermally very stable and does not undergo the expected reductive elimination of alkane.

Graphical abstract: A stable alkyl hydride of a first row transition metal

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Article information

DOI
https://doi.org/10.1039/B301943H
Article type
Communication
Submitted
18 Feb 2003
Accepted
28 Feb 2003
First published
10 Apr 2003

Chem. Commun., 2003, 1164-1165

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A stable alkyl hydride of a first row transition metal

L. A. MacAdams, G. P. Buffone, C. D. Incarvito, J. A. Golen, A. L. Rheingold and K. H. Theopold, Chem. Commun., 2003, 1164 DOI: 10.1039/B301943H

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