Issue 9, 2003
From the journal:

Chemical Communications

Poly(9,9′-spirobifluorene-manganese porphyrin): a new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene†

Cyril Poriel,a   Yann Ferrand,a   Paul le Maux,a   Joëlle Raul-Berthelot*b  and  Gerard Simonneaux*a  

* Corresponding authors

a Laboratoire de Chimie Organométallique et Biologique, UMR CNRS 6509, Université de Rennes 1, 35042 Rennes cedex, France
E-mail: gerard.simonneaux@univ-rennes1.fr
Fax: 02 23 23 56 37
Tel: 02 23 23 62 85

b Laboratoire de Syntèse et électrosynthèse organiques, UMR CNRS 6510, Université de Rennes I, 35042 Rennes cedex, France
E-mail: joelle.rault@univ-rennes1.fr
Fax: 02 23 23 69 55
Tel: 02 23 23 59 64

Abstract

Anodic oxidation of tetraspirobifluorene-manganese porphyrin lead to the coating of the working electrode by insoluble electroactive poly(9,9′-spirobifluorene-manganese porphyrin) films for which electrochemical behaviour and physicochemical properties are described; these polymeric materials are able to catalyze the heterogeneous epoxidation of styrene with iodobenzene diacetate and iodosylbenzene.

Graphical abstract: Poly(9,9′-spirobifluorene-manganese porphyrin): a new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene

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Article information

DOI
https://doi.org/10.1039/B301717F
Article type
Communication
Submitted
13 Feb 2003
Accepted
14 Mar 2003
First published
02 Apr 2003

Chem. Commun., 2003, 1104-1105

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Poly(9,9′-spirobifluorene-manganese porphyrin): a new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene

C. Poriel, Y. Ferrand, P. le Maux, J. Raul-Berthelot and G. Simonneaux, Chem. Commun., 2003, 1104 DOI: 10.1039/B301717F

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