Total synthesis of (±)-dihydrospiniferin-1 via a polyfluoro alkanosulfonyl fluoride induced tandem carbonium ion rearrangement reaction
Abstract
A novel polyfluoroalkanosulfonyl fluoride induced carbonium ion rearrangement reaction of γ-hydroxymethyl cyclohexenone has been used for the total synthesis of (±)dihydrospiniferin 1