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Issue 8, 2003
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High tetraalkylaluminate fluxionality in half-sandwich complexes of the trivalent rare-earth metals

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Abstract

Steric factors govern the formation of half-sandwich complexes (C5Me4R)Ln[N(SiHMe2)2]2 according to acid–base reactions utilising Ln[N(SiHMe2)2]3(thf)2 and substituted cyclopentadienes. Subsequent trimethylaluminium-promoted silylamide elimination produces the first half-sandwich bis(tetramethylaluminate) complexes (C5Me4R)Ln(AlMe4)2.

Graphical abstract: High tetraalkylaluminate fluxionality in half-sandwich complexes of the trivalent rare-earth metals

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Submitted
02 Jan 2003
Accepted
10 Mar 2003
First published
24 Mar 2003

Chem. Commun., 2003, 1008-1009
Article type
Communication

High tetraalkylaluminate fluxionality in half-sandwich complexes of the trivalent rare-earth metals

R. Anwander, M. G. Klimpel, H. Martin Dietrich, D. J. Shorokhov and W. Scherer, Chem. Commun., 2003, 1008
DOI: 10.1039/B212754G

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