Issue 7, 2003
From the journal:

Chemical Communications

A reductive recycle strategy for the facile synthesis of molybdenum(VI) alkylidyne catalysts for alkyne metathesis†

Wei Zhang,a   Stefan Krafta  and  Jeffrey S. Moore*a  

* Corresponding authors

a Roger Adams Laboratory, Departments of Chemistry, Materials Science & Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA
E-mail: js-moore@uiuc.edu
Fax: 1-217-244-8068
Tel: 1-217-244-4024

Abstract

A convenient synthesis of trisamido molybdenum(VI) alkylidyne complexes has been developed, in which the key step is the addition of a geminal dichloride to a trisamido molybdenum(III) complex in the presence of magnesium to continuously recycle unwanted side product 4, selectively generating the desired alkylidyne complexes in high yield.

Graphical abstract: A reductive recycle strategy for the facile synthesis of molybdenum(VI) alkylidyne catalysts for alkyne metathesis

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Article information

DOI
https://doi.org/10.1039/B212405J
Article type
Communication
Submitted
17 Dec 2002
Accepted
13 Feb 2003
First published
27 Feb 2003

Chem. Commun., 2003, 832-833

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A reductive recycle strategy for the facile synthesis of molybdenum(VI) alkylidyne catalysts for alkyne metathesis

W. Zhang, S. Kraft and J. S. Moore, Chem. Commun., 2003, 832 DOI: 10.1039/B212405J

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