Issue 3, 2003
From the journal:

Chemical Communications

Helical templating of polyiodide networks at a binuclear metallo complex†

Caitlin J. Horn,a   Alexander J. Blake,a   Neil R. Champness,a   Alessandra Garau,b   Vito Lippolis,b   Claire Wilsona  and  Martin Schröder*a  

* Corresponding authors

a School of Chemistry, The University of Nottingham, University Park, Nottingham, UK
E-mail: M.Schröder@nottingham.ac.uk

b Dipartimento di Chimica Inorganica ed Analitica, Università di Cagliari, Complesso Universitario di Monserrato, S.S. 554 Bivio per Sestu, Monserrato (Ca), Italy

Abstract

A homobimetallic supramolecular helicate has been prepared from a new multimodal ligand, and used to template the formation of two polyiodide networks, one containing an unprecedented figure-of-eight polyiodide helix, the other dominated by peripheral C–H⋯I polyiodide chain interactions.

Graphical abstract: Helical templating of polyiodide networks at a binuclear metallo complex

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Article information

DOI
https://doi.org/10.1039/B211743F
Article type
Communication
Submitted
26 Nov 2002
Accepted
11 Dec 2002
First published
14 Jan 2003

Chem. Commun., 2003, 312-313

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Helical templating of polyiodide networks at a binuclear metallo complex

C. J. Horn, A. J. Blake, N. R. Champness, A. Garau, V. Lippolis, C. Wilson and M. Schröder, Chem. Commun., 2003, 312 DOI: 10.1039/B211743F

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