Issue 3, 2003
From the journal:

Chemical Communications

A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide†

Darío C. Gerbino,‡a   Eva Hevia,a   Dolores Morales,a   M. Elena Navarro Clemente,§a   Julio Pérez,*a   Lucía Riera,a   Víctor Rieraa  and  Daniel Miguelb  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica-IUQOEM, Facultad de Química-CSIC, Universidad de Oviedo, Oviedo, Spain
E-mail: japm@sauron.quimica.uniovi.es

b Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, Valladolid, Spain

Abstract

A new basic transformation linking two important classes of transition metal compounds; namely, hydroxo and hydrosulfido complexes has been discovered.

Graphical abstract: A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide

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Article information

DOI
https://doi.org/10.1039/B210860G
Article type
Communication
Submitted
05 Nov 2002
Accepted
09 Dec 2002
First published
20 Dec 2002

Chem. Commun., 2003, 328-329

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A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide

D. C. Gerbino, E. Hevia, D. Morales, M. E. N. Clemente, J. Pérez, L. Riera, V. Riera and D. Miguel, Chem. Commun., 2003, 328 DOI: 10.1039/B210860G

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