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Issue 2, 2003
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Catalytic enantioselective allylation with chiral Lewis bases

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Abstract

The advent of chiral Lewis base-promoted allylation of aldehydes has opened a new direction in the catalytic enantioselective construction of homoallylic alcohols. This short review outlines the conceptual framework for the creation of this new process and the interplay of mechanistic investigations and synthetic studies that have conspired to produce a useful new reaction. The current state-of-the-art in catalyst design and application of the reaction in synthesis are briefly illustrated.

Graphical abstract: Catalytic enantioselective allylation with chiral Lewis bases

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Publication details

The article was first published on 24 Dec 2002


Article type: Focus
DOI: 10.1039/B208065F
Chem. Commun., 2003, 167-170

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    Catalytic enantioselective allylation with chiral Lewis bases

    S. E. Denmark and J. Fu, Chem. Commun., 2003, 167
    DOI: 10.1039/B208065F

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