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Issue 22, 2003
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Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene

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Abstract

Treatment of the terminal titanium–phosphinidene (Nacnac)Ti[double bond, length as m-dash]PMes*(CH2tBu) (Nacnac = [2,6-iPr2C6H3]–NC(CH3)CHC(CH3)N[2,6-iPr2C6H3], Mes* = 2,4,6-tBu3C6H2) with CNtBu and N2CPh2, in pentane at −35 °C, affords η2-(N,C)-phosphaazaallene and phosphinylimide complexes, respectively.

Graphical abstract: Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene

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Publication details

The article was received on 23 Sep 2003, accepted on 02 Oct 2003 and first published on 14 Oct 2003


Article type: Communication
DOI: 10.1039/B311748K
Dalton Trans., 2003, 4228-4229

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    Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene

    F. Basuli, L. A. Watson, J. C. Huffman and D. J. Mindiola, Dalton Trans., 2003, 4228
    DOI: 10.1039/B311748K

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