Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene†
Abstract
Treatment of the terminal titanium–phosphinidene (Nacnac)TiPMes*(CH2tBu)
(Nacnac−
=
[2,6-iPr2C6H3]–NC(CH3)CHC(CH3)N[2,6-iPr2C6H3], Mes*−
= 2,4,6-tBu3C6H2) with CNtBu and N2CPh2, in