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Issue 19, 2003
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Synthesis, structural and theoretical studies of an iron–gallium(i) heterocycle complex: Analogies with N-heterocyclic carbene chemistry

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Abstract

The first iron complex of an anionic gallium N-heterocyclic carbene analogue, [Fe(CO)4{Ga[N(Ar)C(H)]2}] Ar = C6H3Pri2-2,6, has been prepared and shown to have an unusual polymeric structure in the solid state; theoretical studies have pointed toward minimal Fe → Ga back-bonding in this complex.

Graphical abstract: Synthesis, structural and theoretical studies of an iron–gallium(i) heterocycle complex: Analogies with N-heterocyclic carbene chemistry

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Article information


Submitted
23 Jul 2003
Accepted
26 Aug 2003
First published
28 Aug 2003

Dalton Trans., 2003, 3673-3674
Article type
Communication

Synthesis, structural and theoretical studies of an iron–gallium(I) heterocycle complex: Analogies with N-heterocyclic carbene chemistry

R. J. Baker, C. Jones and J. A. Platts, Dalton Trans., 2003, 3673
DOI: 10.1039/B308616J

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