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Issue 17, 2003

The role of 1,2,4,5-tetrazine rings in π–π stacking interactions

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Abstract

The crystal structures of 3,6-dipyridin-3-yl-(1,2,4,5)-tetrazine, 3,6-dipyridin-4-yl-(1,2,4,5)-tetrazine and 3,6-dipyrazin-2-yl-(1,2,4,5)-tetrazine are reported. The packing arrangements of these three compounds containing 1,2,4,5-tetrazine rings are examined. The 1,2,4,5-tetrazine rings are electron deficient with respect to phenyl rings and the effect this has upon the observed packing motifs is discussed.

Graphical abstract: The role of 1,2,4,5-tetrazine rings in π–π stacking interactions

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Supplementary files

Article information


Submitted
25 Feb 2003
Accepted
13 Mar 2003
First published
25 Mar 2003

CrystEngComm, 2003,5, 82-86
Article type
Paper

The role of 1,2,4,5-tetrazine rings in π–π stacking interactions

N. S. Oxtoby, A. J. Blake, N. R. Champness and C. Wilson, CrystEngComm, 2003, 5, 82
DOI: 10.1039/B302187D

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