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Issue 60, 2003

Involving metals in halogenhalogen interactions: second-sphere Lewis acid ligands for perhalometallate ions (M–X⋯X′–C)

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Abstract

Lewis-acidic halocarbon groups (X–C) serve as effective second-sphere ligands for perhalometallate ions and provide an alternative means to hydrogen bonds for developing the supramolecular chemistry of such ions, exemplified here by short directional M–X⋯X′–C halogen bond linkages used in conjunction with hydrogen bonds for crystal synthesis.

Graphical abstract: Involving metals in halogen–halogen interactions: second-sphere Lewis acid ligands for perhalometallate ions (M–X⋯X′–C)

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Publication details

The article was received on 28 Aug 2003, accepted on 01 Sep 2003 and first published on 16 Sep 2003


Article type: Communication
DOI: 10.1039/B310412E
CrystEngComm, 2003,5, 343-345

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    Involving metals in halogenhalogen interactions: second-sphere Lewis acid ligands for perhalometallate ions (M–X⋯X′–C)

    L. Brammer, G. Mínguez Espallargas and H. Adams, CrystEngComm, 2003, 5, 343
    DOI: 10.1039/B310412E

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