Jump to main content
Jump to site search

Issue 22, 2003
Previous Article Next Article

Different thermal reactivity of a 1,2-thiaphospholo[a]phosphirane in free and metal carbonyl complexed form

Author affiliations

Abstract

The W(CO)5 and Fe(CO)4 complexes of the bicyclic phosphirane 3,5,6,6-tetraphenyl-1-phospha-2-thiabicyclo[3.1.0]hex-3-ene undergo a thermal 2-phenylphosphirane → dihydrophosphaisoindole ring expansion, while the free phosphirane suffers both a [2 + 1] cycloreversion and a fragmentation yielding a butadienyl sulfide.

Graphical abstract: Different thermal reactivity of a 1,2-thiaphospholo[a]phosphirane in free and metal carbonyl complexed form

Back to tab navigation

Supplementary files

Article information


Submitted
25 Aug 2003
Accepted
23 Sep 2003
First published
14 Oct 2003

Chem. Commun., 2003, 2794-2795
Article type
Communication

Different thermal reactivity of a 1,2-thiaphospholo[a]phosphirane in free and metal carbonyl complexed form

T. Jikyo and G. Maas, Chem. Commun., 2003, 2794
DOI: 10.1039/B310256D

Social activity

Search articles by author

Spotlight

Advertisements