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Issue 20, 2003
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Stereochemical elucidation of the 1,4 polyketide amphidinoketide I

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Abstract

The relative and absolute stereochemistry of amphidinoketide I has been determined by the total synthesis of all the diastereoisomers. Molecular modelling suggests that the natural product is not the thermodynamically preferred diastereoisomer.

Graphical abstract: Stereochemical elucidation of the 1,4 polyketide amphidinoketide I

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Article information


Submitted
31 Jul 2003
Accepted
12 Sep 2003
First published
23 Sep 2003

Chem. Commun., 2003, 2616-2617
Article type
Communication

Stereochemical elucidation of the 1,4 polyketide amphidinoketide I

L. M. Walsh and J. M. Goodman, Chem. Commun., 2003, 2616
DOI: 10.1039/B309104J

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