Issue 20, 2003
From the journal:

Chemical Communications

Stereochemical elucidation of the 1,4 polyketide amphidinoketide I

Louise M Walsha  and  Jonathan M Goodman*a  

* Corresponding authors

a Unilever Centre for Molecular Informatics, Department of Chemistry, Lensfield Road, Cambridge, UK
E-mail: J.M.Goodman@ch.cam.ac.uk
Fax: 44 1223 336362
Tel: 44 1223 336364

Abstract

The relative and absolute stereochemistry of amphidinoketide I has been determined by the total synthesis of all the diastereoisomers. Molecular modelling suggests that the natural product is not the thermodynamically preferred diastereoisomer.

Graphical abstract: Stereochemical elucidation of the 1,4 polyketide amphidinoketide I

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Article information

DOI
https://doi.org/10.1039/B309104J
Article type
Communication
Submitted
31 Jul 2003
Accepted
12 Sep 2003
First published
23 Sep 2003

Chem. Commun., 2003, 2616-2617

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Stereochemical elucidation of the 1,4 polyketide amphidinoketide I

L. M. Walsh and J. M. Goodman, Chem. Commun., 2003, 2616 DOI: 10.1039/B309104J

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