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Issue 13, 2003
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Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide

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Abstract

One electron oxidation of the bis-anilido titanium(III) complex (Nacnac)Ti(NHAr)2 (Nacnac = ArNC(CH3)CHC(CH3)NAr, Ar = 2,6-(CHMe2)2C6H3) with AgOTf affords the cation [(Nacnac)Ti(NHAr)2][OTf] which is isolated and shown to gradually transform, by α-hydrogen abstraction, to the terminal and four-coordinate titanium imide (Nacnac)Ti[double bond, length as m-dash]NAr(OTf).

Graphical abstract: Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide

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Publication details

The article was received on 26 Apr 2003, accepted on 13 May 2003 and first published on 02 Jun 2003


Article type: Communication
DOI: 10.1039/B304633H
Chem. Commun., 2003, 1554-1555

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    Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide

    F. Basuli, B. C. Bailey, J. C. Huffman and D. J. Mindiola, Chem. Commun., 2003, 1554
    DOI: 10.1039/B304633H

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